THEORETICAL STUDYING SPECTRAL CHARACTERISTICS OF Tm ATOM WITHIN OPTIMIZED RELATIVISTIC MANY-BODY THEORY

نویسندگان

چکیده

Theoretical studying Rydberg spectrum of complex lanthanide atom Tm has been performed within the relativistic many-body perturbation theory and generalized energy approach. The zeroth approximation is provided by optimized Dirac-Kohn-Sham-Breit ones. Optimization fulfilled means introduction special gauge parameter to Fock Kohn-Sham exchange potentials further minimization gauge-non-invariant contributions into radiation width atomic levels with using orbital sets, generated corresponding Hamiltonian. calculated energies widths autoionization resonant states 4f--1j 6s(J12)nsnp[J] n=25-35 are presented compared known theoretical results, received other approaches. Two main types resonances decay, namely, classic Beutler-Fano decay channel a new Ivanov et al reorientation-type ar4e studied. It noted that, for example, considered values n, occurs along both channels, it extremely difficult understand priori which them dominant.

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ژورنال

عنوان ژورنال: ???????????????

سال: 2022

ISSN: ['0235-2435']

DOI: https://doi.org/10.18524/0235-2435.2021.30.262891